Product ID:CEMENTED CARBIDE GRADE CC690
MSDS Date:01/01/1992
FSC:9650
NIIN:00N083790
MSDS Number: CGRJZ

SANDVIK COROMANT CO

1702 NEVINS RD
FAIR LAWN, NJ 07410
US

Emergency Phone: 800-424-9300(CHEMTREC)

Info Phone: 201-794-5000

Cage: 17411

SANDVIK COROMANT CO

FAIR LAWN, NJ 07410-2803 US

Telephone: 201-797-5000

Cage: 17411

SILICON NITRIDE

CAS: 12033-89-5

Fraction By Weight: 91%

OSHA PEL N/K

ACGIH TLV: N/K

YTTRIUM TRIOXIDE; (YTTRIUM OXIDE)

CAS: 1314-36-9

RTECS: ZG3850000

Fraction By Weight: 6%

OSHA PEL 1 MG/M3 (MFR)

ACGIH TLV: 1 MG/M3 (MFR)

ZIRCONIUM OXIDE (MFR INVALID CAS #7446-67-7)

CAS: 1314-23-4

RTECS: ZH8800000

Fraction By Weight: 5%

OSHA PEL N/K

ACGIH TLV: 5 MG/M3 (MFR)

IRON (III) OXIDE; (IRON OXIDE)

CAS: 1309-37-1

RTECS: NO7400000

Fraction By Weight: 23%

OSHA PEL 10 MG/M3 (FE)

ACGIH TLV: 5 MG/M3 FUME (FE)

3); (ALUMINUM OXIDE) (SARA 313)

CAS: 1344-28-1

RTECS: BD1200000

Fraction By Weight: 1.0%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

MANGANESE; (MAGNESIUM OXIDE) (SARA 313)

CAS: 7439-96-5

RTECS: OO9275000

Fraction By Weight: 1%

OSHA PEL 5 MG/M3 DUST, C

ACGIH TLV: 5 MG/M3 DUST

IF AIRBORNE DUST IS GENERATED, USE AN

RTECS: 9999999ZZ

WASH HANDS THOROUGHLY AFTER HANDLING, BEFORE

RTECS: 9999999ZZ

SHIFT. DO NOT SHAKE CLTHG, RAGS OR OTHER ITEMS TO

RTECS: 9999999ZZ

VACUUMING (W/APPROPRIATE FILTER) THE CLTHG, RAGS OR

RTECS: 9999999ZZ

FOR INDIVIDUALS REGULARLY EXPOSED TO DUST OR MIST.

RTECS: 9999999ZZ

TABLE 1. FOLLOWING TYPE RESPS SHOULD BE USED AT

RTECS: 9999999ZZ

PURIFYING RESP W/DUST/MIST/FUME OR HIGH EFFICIENCY

RTECS: 9999999ZZ

PURIFYING RESP W/HIGH EFFICIENCY FILTER. UP TO 10

RTECS: 9999999ZZ

RESP W/HIGH EFFICIENCY FILTER. UP TO 100 MG/M3

RTECS: 9999999ZZ

IN POSITIVE PRESSURE MODE. ABOVE 100 MG/M3 (SIO*2)

RTECS: 9999999ZZ

OPERATED IN POSITIVE PRESSURE MODE OR A SUPPLIED

RTECS: 9999999ZZ

PRESSURE MODE W/AUXILIARY SELF CONTAINED AIR

RTECS: 9999999ZZ

WHICH DO NOT EXCEED THE PEL OR TLV. IF SUCH EQUIPMENT

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EXPOS TO DUST/FUMES CAN IRRIT
EYES, NOSE & THROAT. CHRONIC: IT IS SUSPECTED THAT RPTD EXPOS TO LG
AMTS OF ALUMINUM &/OR ZIRCONIUM DUST MAY DMG LUNGS, LEADING TO
PNEUM &/OR TO SCARRING OF LUNGS. THESE CNDTNS CAN BE FATAL. SYMPS
INCL SHORTNESS OF BREATH, WHEEZ, PRODUCTIVE COUGH & TIGHTNESS OF
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: CHEST. PARTICLES OF ALUMINUM
DEPOSITED IN EYES MAY CAUSE NECROSIS OF CORNEA. YTTRIUM CMPDS HAVE
BEEN FOUND TO CAUSE LIVER DMG IN EXPERIMENTAL ANIMALS. IN LIMITED
ANIMAL STUDIES, FIBROUS SILI CON NITRIDE HAS BEEN FOUND TO HAVE
PROPERTIES SIMILAR TO SILICON DIOXIDE (ALPHA QUARTZ). UNTIL FURTHER
INFO IS (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INGEST: CALL MD IMMED . INHAL: IF SYMPS OF PULMONARY
INVOLVEMENT DEVELOP (COUGH, WHEEZ, SHORTNESS OF BREATH, ETC),
REMOVE FROM EXPOS & SEEK MED ATTN. SKIN: IF IRRIT/RASH OCCURS,
THOROUGHLY WASH AFFECTED AREA W/SOAP & WATER & ISOLATE FROM EXPOS.
IF IRRIT/RASH PERSISTS, SEEK MED ATTN. EYES: IF IRRIT OCCURS, FLUSH
W/LARGE AMTS OF WATER FOR AT LEAST 15 MIN. IF IRRIT PERSISTS, SEEK
MED ATTN.

Extinguishing Media:USE A DRY POWDER EXTINGUISHER APPROPRIATE FOR USE
WITH METAL DUST FIRES.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:UNDER RARE FAVORING CONDITIONS OF
PARTICLE SIZE AND DISPERSION, DUSTS FROM GRINDING MAY BE
SPONTANEOUSLY COMBUSTIBLE OR EXPLOSIVE.

Spill Release Procedures:VENT AREA OF SPILL. CLEAN UP USING METHODS
WHICH AVOID DUST GENERATION SUCH AS: VACUUM CLEANER EQUIPPED W/HIGH
EFFICIENCY PARTICULATE ABSOLUTE (HEPA) FILTER TO PVNT AIRBORNE DUST
LEVELS WHICH EXCEED P EL OR TLV, WET DUST MOP OR WET CLEAN-UP. (ING
7)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:MAINTAIN GOOD HOUSEKEEPING PROCEDURES
TO PREVENT DUST ACCUMULATION DURING GRINDING. AVOID DUST INHALATION
AND DIRECT SKIN CONTACT WITH DUST.
Other Precautions:CLEAN UP USING METHODS WHICH AVOID DUST GENERATION
SUCH AS VACUUM (W/APPROP FILTER TO PVNT AIRBORNE DUST LEVELS WHICH
EXCEED PEL/TLV), WET DUST MOP OR WET CLEAN-UP. IF AIRBORNE DUST IS
GENERATED, USE AN APPROP NIOSH APPRVD RESP. (ING 8)

Respiratory Protection:USE APPROP NIOSH APPRVD RESP IF AIRBORNE DUST
CONCS EXCEED APPROP PEL OR TLV. ALL APPROP REQS AS SET FORTH IN 29
CFR 1910.134 SHOULD BE MET. PROTECTION FACTORS FOR RESPS RECOM ARE
BASED UPON THOSE AS LISTED IN 29 CFR 1910.1001(G), (ING 12)
Ventilation:USE LOCAL EXHAUST VENT WHICH IS ADEQUATE TO LIMIT PERSONAL
EXPOSURE TO RESPIRABLE AIRBORNE DUST TO LEVELS (ING 19)
Protective Gloves:IMPERVIOUS GLOVES /BARRIER CREAMS.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . PRIOR
TO APPLYING BARRIER CREAM OR USE OF PROT GLOVES, WASH THOROUGHLY.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MATL TO AVOID: VIOLENT REACTION. CNTCT OF DUST W/OXIDIZERS MAY CAUSE
FIRE OR EXPLOSION. THIS PROD MAY REACT VIOLENTLY W/STRONG ACIDS.
HAZ DECOMP PRODS: BE PRDCED BY HEATING ALUMINUM NITRIDE. EFTS OF O
VEREXP: AVAIL FOR SILICON NITRIDE, MFR RECOMS LEVELS BE MAINTAINED
BELOW SILICON DIOXIDE PEL OF 1 MG/M3 RESPIRABLE DUST.

Spec Gravity:11-15.5(H*2O=1)
Solubility in Water:INSOLUBLE
Appearance and Odor:BLACK METEAL; NO ODOR.
Percent Volatiles by Volume:0

Stability Indicator/Materials to Avoid:YES
ALUMINUM NITRIDE WILL REACT W/WATER OR STEAM TO PRDCE TOX OR CORR
FUMES. CNTCT OF YTTRIUM W/HALOGENS MAY PRDCE (SUPDAT)
Stability Condition to Avoid:THIS PRODUCT IS STABLE UNDER NORMAL USE
CONDITIONS.
Hazardous Decomposition Products:ALUMINUM OXIDE REACTING W/HALOCARBON
VAPS AT HIGH TEMPS MAY PRDCE TOX HYDROGEN CHLORIDE & PHOSGENE.
AMMONIA MAY (SUPDAT)

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH APPROPRIATE
FEDERAL, STATE AND LOCAL GOVERNMENT REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.